High-resolution voltammetric determination of carmoisine, allura red and brilliant blue on their simultaneous presence in food products

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Рұқсат ақылы немесе тек жазылушылар үшін

Аннотация

A voltammetric sensor is developed based on a carbon fiber planar electrode modified with a nanocomposite for the simultaneous determination of the synthetic food dyes carmoisine (Car), allura red (AR), and brilliant blue (BB). The nanocomposite includes nickel oxide nanoparticles synthesized using a strawberry leaf extract, graphene nanoplates and the cationic surfactant cetyltrimethylammonium bromide. The modified electrode exhibits enhanced signal responses for all three colorants at an improved resolution. Electrochemical oxidation proceeds irreversibly, governed by surface-controlled processes in the cases of Car and BB, and by diffusion-controlled processes in the case of AR. The proposed method enables the simultaneous voltammetric determination of Car, AR, and BB using the developed sensor. The limits of detection for Car, AR and BB are 0.05, 0.08 and 0.15 μM, respectively. Under the selected conditions for recording differential pulse voltammetry signals, real samples including soft drinks, syrup, and marshmallows were successfully analyzed, yielding accuracy values ranging from 95 to 104%.

Толық мәтін

Рұқсат жабық

Авторлар туралы

E. Khamzina

Ural State University of Economics

Email: sny@usue.ru
Ресей, Ekaterinburg

M. Bukharinova

Ural State University of Economics

Email: sny@usue.ru
Ресей, Ekaterinburg

N. Stozhko

Ural State University of Economics

Хат алмасуға жауапты Автор.
Email: sny@usue.ru
Ресей, Ekaterinburg

V. Kolotygina

Ural State University of Economics

Email: sny@usue.ru
Ресей, Ekaterinburg

Әдебиет тізімі

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2. Fig. 1. (a) Cyclic voltammograms recorded using unmodified (1, 2) and modified carbon fiber electrodes (3 – graphene/CFE, 4 – NiO–graphene/CFE, 5 – CTAB–NiO–graphene/CFE) in the absence (dashed) and presence (solid lines) of an equimolar mixture of 10 µM dyes Car, KO, SB. (b) Cyclic voltammograms recorded using carbon fiber electrodes modified with a mixture of graphene and metal oxide nanoparticles (1 – ZnO, 2 – Co3O4, 3 – NiO) in the presence of an equimolar mixture of 10 µM dyes Car, KO, SB. Background: BRB pH 7, ν = 25 mV/s.

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3. Fig. 2. Effect of NiO content in the composite modifier on the oxidation peak potential difference (a) of dyes Car and KO (ΔE1), KO and SB (ΔE2), and their current (b) on the CTAB–NiO–graphene/CFE.

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4. Fig. 3. Effect of CTAB concentration in the composite modifier on the oxidation peak potential difference (a) of dyes Car and KO (ΔE1), KO and SB (ΔE2), and their current (b) on the CTAB–NiO–graphene/CFE.

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5. Fig. 4. (a) Cyclic voltammograms of 1.0 mM K4[Fe(CN)6] in 0.1 M KCl solution; (b) I = ƒ (1/t1/2) dependencies obtained from corresponding chronoamperograms in the same solution on different electrodes at 0.7 V.

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6. Fig. 5. Effect of background solution pH on (a) oxidation peak potentials of dyes and (b) peak potential differences ΔE1 and ΔE2 between them.

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7. Fig. 6. Dependencies (a) lg Ip = ƒ (lg ν) and (b) Ep = ƒ (lg ν) for Car, KO, and SB.

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8. Fig. 7. Differential pulse voltammograms (with baseline correction) of various concentrations of Car, KO, and SB in the simultaneous presence in phosphate buffer solution at pH 7, ν = 50 mV/s.

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