Особенности формирования элементного “образа” в цепочке почва–виноград–вино и изучение взаимосвязи вещественных форм элементов
- Авторы: Темердашев З.А.1, Абакумов А.Г.1, Халафян А.А.1, Шелудько О.Н.2
-
Учреждения:
- Кубанский государственный университет
- Северо-Кавказский федеральный научный центр садоводства, виноградарства, виноделия
- Выпуск: Том 79, № 11 (2024)
- Страницы: 1195-1209
- Раздел: ОРИГИНАЛЬНЫЕ СТАТЬИ
- Статья получена: 16.06.2025
- URL: https://vestnik.nvsu.ru/0044-4502/article/view/684629
- DOI: https://doi.org/10.31857/S0044450224110063
- EDN: https://elibrary.ru/swrvwa
- ID: 684629
Цитировать
Аннотация
Методами ИСП-спектрометрического и хемометрического анализа изучена возможность установления взаимосвязи распределения валового содержания и подвижных форм элементов почв виноградников. Подлинность вин по сортовому и географическому признаку изучили по взаимосвязи между элементным составом вина, винограда и почвы с места произрастания винограда. Характер поступления элементов в цепочке почва–виноград и степень усвоения подвижных форм элементов почв ягодами винограда оценивали также по показателю “биологический коэффициент поглощения”. Каждый сорт винограда формировал элементный образ за счет индивидуального характера усвоения изучаемых элементов. Содержание K, Rb, и Ti в образцах винограда оказалось больше, чем концентрации подвижных форм этих элементов в почве вне зависимости от сорта. Диаграммы рассеяния канонических значений и проекции наблюдений на факторную плоскость, построенные методами многомерного статистического анализа по концентрациям элементов, показали, что каждый сорт винограда локализован в определенной части плоскости, образуя группы однородных объектов (кластеры). Вклад элементов в модель дискриминации винограда по сортовому признаку убывает в последовательности: Mo, Cu, K, Ni, Ba, Ca, Pb, Li, Mg, Fe, Ti, Zn, Rb, Al, V; а по региональному признаку – Rb, Al, K, Sr, Co, Na, Pb, Ca и Ni. Полученные результаты могут быть использованы при установлении маркеров, определяющих сортовую и региональную принадлежность вин.
Об авторах
З. А. Темердашев
Кубанский государственный университет
Автор, ответственный за переписку.
Email: temza@kubsu.ru
факультет химии и высоких технологий
Россия, ул. Ставропольская, 149, Краснодар, 350040А. Г. Абакумов
Кубанский государственный университет
Email: temza@kubsu.ru
факультет химии и высоких технологий
Россия, ул. Ставропольская, 149, Краснодар, 350040А. А. Халафян
Кубанский государственный университет
Email: temza@kubsu.ru
факультет химии и высоких технологий
Россия, ул. Ставропольская, 149, Краснодар, 350040О. Н. Шелудько
Северо-Кавказский федеральный научный центр садоводства, виноградарства, виноделия
Email: temza@kubsu.ru
Россия, ул. 40-летия Победы, 39, Краснодар, 350072
Список литературы
- Resolution OIV/VITI 333/2010. Definition of vitivinicultural “terroir”. https://www.oiv.int/public/medias/379/viti-2010-1-en.pdf (дата обращения 02.06.2024).
- Resolution OIV CST 1/2007. Traceability Guidelines in the Vitivinicultural Sector. https://www.oiv.int/public/medias/2084/cst-1-2007-en.pdf (дата обращения 02.06.2024).
- Ribéreau-Gayon P., Glories Y., Maujean A., Dubourdieu D. The Chemistry of Wine: Stabilization and Treatments. Handbook of Enology. 2nd Ed. Chichester, England: John Wiley & Sons Ltd., 2006. 450 p.
- Hao X., Gao F., Wu H., Song Y., Zhang L., Li H., Wang H. From soil to grape and wine: Geographical variations in elemental profiles in different Chinese regions // Foods. 2021. V. 10. Article 3108. https://doi.org/10.3390/foods10123108
- Maltman A. Minerality in wine: A geological perspective // J. Wine Res. 2013. V. 24. P. 169. https://doi.org/10.1080/09571264.2013.793176
- Marschner P. Marschner’s Mineral Nutrition of Higher Plants. 3rd Ed. London, UK: Elsevier, 2012. 643 p.
- Jiménez-Ballesta R., Bravo S., Amorós J.A., Pérez-de-los-Reyes C., García-Pradas J., Sanchez M., García-Navarro F.J. Soil and leaf mineral element contents in mediterranean vineyards: Bioaccumulation and potential soil pollution // Water, Air, Soil Pollut. 2022. V. 233. Article 20. https://doi.org/10.1007/s11270-021-05485-6
- Blotevogel S., Schreck E., Audry S., Saldi G.D., Viers J., Courjalt-Rade P., et al. Contribution of soil elemental contents and Cu and Sr isotope ratios to the understanding of pedogenetic processes and mechanisms involved in the soil-to-grape transfer (Soave vineyard, Italy) // Geoderma. 2019. V. 343. P. 72. https://doi.org/10.1016/j.geoderma.2019.02.015
- Ramirez P.M., Ibanez J.D.I.H. Nutrient content of vineyard leaves after prolonged treated wastewater irrigation // Agronomy. 2023. V. 13. Article 620. https://doi.org/10.3390/agronomy13030620
- Parr W., Maltman A., Easton S., Ballester J. Minerality in wine: Towards the reality behind the myths // Beverages. 2018. V. 4. Article 77. https://doi.org/10.3390/beverages4040077
- Kabata-Pendias A. Trace Elements in Soils and Plants. 4th Ed. Boca Raton, USA: CRC Press, 2010. 548 p. https://doi.org/10.1201/b10158
- Blotevogel S., Schreck E., Laplanche C., Besson P., Saurin N., Audry S., et al. Soil chemistry and meteorological conditions influence the elemental profiles of West European wines // Food Chem. 2019. V. 298. Article 125033. https://doi.org/10.1016/j.foodchem.2019.125033
- Абакумов А.Г., Титаренко В.О., Халафян А.А., Темердашев З.А., Каунова А.А. Установление сортовой принадлежности винограда по выявленным элементам-маркерам в ягоде и различных ее составляющих частях // Аналитика и контроль. 2019. Т. 23. С. 61. https://doi.org/10.15826/analitika.2019.23.1.002
- Van Leeuwen C. Terroir: The effect of the physical environment on vine growth, grape ripening and wine sensory attributes / Managing Wine Quality. Viticulture and Wine Quality. Sawston, UK: Woodhead Publishing Ltd, 2010. 548 p. https://doi.org/10.1201/b10158
- Reynolds A.G., Taylor G., Savigny C. Defining Niagara terroir by chemical and sensory analysis of Chardonnay wines from various soil textures and vine sizes // Am. J. Enol. Vitic. 2013. V. 64. P. 180.
- Tramontini S., Leeuwen C., Domec J.C., Destrac-Irvine A., Basteau C., Vitsli M., et al. Impact of soil texture and water availability on the hydraulic control of plant and grape-berry development // Plant Soil. 2013. V. 368. P. 215.
- Wang R., Sun Q., Chang Q. Soil types effect on grape and wine composition in Helan mountain area of Ningxia // PLoS One. 2015. V. 10. Article e0116690. https://doi.org/10.1371/journal.pone.0116690
- Fernández-Marín M.I., Guerrero R.F., García-Parrilla M.C., Puertas B., Ramírez P., Cantos-Villar E. Terroir and variety: Two key factors for obtaining stilbene-enriched grapes // J. Food Compos. Anal. 2013. V. 31. P.191. https://doi.org/10.1016/j.jfca.2013.05.009
- Jiang B., Xi Z., Luo M., Zhang Z. Comparison on aroma compounds in Cabernet Sauvignon and Merlot wines from four wine grape-growing regions in China // Int. Food Res. 2013. V. 51. P. 482. https://doi.org/10.1016/j.foodres.2013.01.001
- Temerdashev Z.A., Abakumov A.G., Kaunova A.A., Shelud’ko O.N., Tsyupko T.G. Assessment of quality and region of origin of wines // J. Anal. Chem. 2023. V. 78. № 12. P. 1724. https://doi.org/10.1134/S1061934823120171)
- Temerdashev Z., Khalafyan A., Abakumov A., Bolshov M., Akin'shina V., Kaunova A. Authentication of selected white wines by geographical origin using ICP spectrometric and chemometric analysis // Heliyon. 2024. V. 10. Article e29607. https://doi.org/10.1016/j.heliyon.2024.e29607
- Fabani M.P., Toro M.E., Vázquez F., Díaz M.P., Wunderlin D.A. Differential absorption of metals from soil to diverse vine varieties from the Valley of Tulum (Argentina): Consequences to evaluate wine provenance // J. Agric. Food. Chem. 2009. V. 57. P. 7409. https://doi.org/10.1021/jf901572k
- Martin A.E., Watling R.J., Lee G.S. The multi-element determination of Australian wines // Food Chem. 2012. V. 133. P. 1081. https://doi.org/10.1016/j.foodchem.2012.02.013
- Dutra S.V., Adami L., Marcon A.R., Carnieli G.J., Roani C.A., Spinelli F.R., et al. Determination of the geographical origin of Brazilian wines by isotope and mineral analysis // Anal. Bioanal. Chem. 2011. V. 401. P. 1571. https://doi.org/10.1007/s00216-011-5181-2
- Gómez M.D. M.C., Feldmann I., Jakubowski N., Andersson J.T. Classification of German white wines and certified brand of origin by multielement quantitation and pattern recognition techniques // J. Agric. Food Chem. 2004. V. 52. P. 2962. https://doi.org/10.1021/jf035120f
- D’Antone C., Punturo R., Vaccaro C. Rare earth elements distribution in grapevine varieties grown on volcanic soils: An example from Mount Etna (Sicily, Italy) // Environ. Monit. Assess. 2017. V. 189. Article 160. https://doi.org/10.1007/s10661-017-5878-6
- Cabrita M.J., Martins N., Barrulas P., Garcia R., Dias C.B., Pérez-Álvarez E.P., et al. Multi-element composition of red, white and palhete amphora wines from Alentejo by ICPMS // Food Control. 2018. V. 92. P. 80. https://doi.org/10.1016/j.foodcont.2018.04.041
- Dinca O.R., Ionete R.E., Costinel D., Geana I.E., Popescu R., Stefanescu I., Radu G.L. Regional and vintage discrimination of Romanian wines based on elemental and isotopic fingerprinting // Food Anal. Methods. 2016. V. 9. P. 2406. https://doi.org/10.1007/s12161-016-0404-y
- Jurado J.M., Alcázar Á., Palacios-Morillo A., de Pablos F. Classification of Spanish DO white wines according to their elemental profile by means of support vector machines // Food Chem. 2012. V. 135. P. 898. https://doi.org/10.1016/j.foodchem.2012.06.017
- Hu X.-Z., Liu S.-Q., Li X.-H., Wang C.-X., Ni X.-L., Liu X., et al. Geographical origin traceability of Cabernet Sauvignon wines based on Infrared fingerprint technology combined with chemometrics // Sci. Rep. 2019. V. 9. Article 8256. https://doi.org/10.1038/s41598-019-44521-8
- Temerdashev Z., Abakumov A., Khalafyan A., Bolshov M., Lukyanov A., Vasilyev A., Gipich E. The influence of the soil profile on the formation of the elemental image of grapes and wine of the Cabernet Sauvignon variety // Molecules. 2024. V. 29. Article 2251. https://doi.org/10.3390/molecules29102251
- Bevin C.J., Dambergs R.G., Fergusson A.J., Cozzolino D. Varietal discrimination of Australian wines by means of mid-infrared spectroscopy and multivariate analysis // Anal. Chim. Acta. 2008. V. 621. P. 19. https://doi.org/10.1016/j.aca.2007.10.042
- Pohl P. What do metals tell us about wine? // Trends Anal. Chem. 2007. V. 26. P. 941. https://doi.org/10.1016/j.trac.2007.07.005
- Catarino S., Madeira M., Monteiro F., Caldeira I., Bruno de Sousa R. Curvelo-Garcia A. Mineral composition through soil-wine system of Portuguese vineyards and its potential for wine traceability // Beverages. 2018. V. 4. Article 85. https://doi.org/10.3390/beverages4040085
- Temerdashev Z., Abakumov A., Bolshov M., Khalafyan A., Ageeva N., Vasilyev A., Ramazanov A. Instrumental assessment of the formation of the elemental composition of wines with various bentonite clays // Microchem. J. 2022. V. 175. Article 107145. https://doi.org/10.1016/j.microc.2021.107145
- Temerdashev Z., Bolshov M., Abakumov A., Khalafyan A., Kaunova A., Vasilyev A., Sheludko O., Ramazanov A. Can rare earth elements be considered as markers of the varietal and geographical origin of wines? // Molecules. 2023. V. 28. Article 4319. https://doi.org/10.3390/molecules28114319
- Castiñeira M., Brandt R., Jakubowski N., Andersson J.T. Changes of the metal composition in German white wines through the winemaking process. A study of 63 elements by inductively coupled plasma–mass spectrometry // J. Agric. Food Chem. 2004. V. 52. № 10. P. 2953. https://doi.org/10.1021/jf035119g
- Redan B.W. Processing aids in food and beverage manufacturing: potential source of elemental and trace metal contaminants // J. Agric. Food Chem. 2020. V. 68. P 13001. https://doi.org/10.1021/acs.jafc.9b08066
- Catarino S., Madeira M., Monteiro F., Rocha F., Curvelo-Garcia A.S., de Sousa R.B. Effect of bentonite characteristics on the elemental composition of wine // J. Agric. Food Chem. 2008. V. 56. № 1. P. 158. https://doi.org/10.1021/jf0720180
- Mihucz V.G., Done C.J., Tatár E., Virág I., Záray G., Baiulescu E.G. Influence of different bentonites on the rare earth element concentrations of clarified Romanian wines // Talanta. 2006. V. 70. P. 984. https://doi.org/10.1016/j.talanta.2006.05.080
- Zhao H., Tang J., Yang Q. Effects of geographical origin, variety, harvest season, and their interactions on multi-elements in cereal, tuber, and legume crops for authenticity // J. Food Compos. Anal. 2021. V. 100. Article 103900. https://doi.org/10.1016/j.jfca.2021.103900
- Bronzi B., Brilli C., Beone G., Fontanella M., Ballabio D., Todeschini R., et al. Geographical identification of Chianti red wine based on ICP-MS element composition // Food Chem. 2020. Article 126248. https://doi.org/10.1016/j.foodchem.2020.126248
- Catarino S., Curvelo-Garcia A.S., Bruno de Sousa R. Contaminant elements in wines // Ciência Téc. Vitiv. 2008. V. 23. P. 3.
- Wucherpfennig K. Wines. Production of Table Wines / Encyclopedia of Food Sciences and Nutrition. Amsterdam: Elsevier, 2003. p. 6195.
- Yang L., Ren Q., Zheng K., Jiao Z., Ruan X., Wang Y. Migration of heavy metals in the soil-grape system and potential health risk assessment // Sci. Total Environ. 2022. V. 806. Article 150646. https://doi.org/10.1016/j.scitotenv.2021.150646
- Bertin C., Yang X., Weston L.A. The role of root exudates and allelochemicals in the rhizosphere // Plant Soil. 2003. V. 256. P. 67. https://doi.org/10.1023/A:1026290508166
- Темердашев З.А.,. Абакумов А.Г., Халафян А.А, Агеева Н.М. Взаимосвязи между элементным составом винограда, почвы с места его произрастания и вина // Заводск. лаборатория. Диагностика материалов. 2021. Т. 87. № 11. С. 11. https://doi.org/10.26896/1028-6861-2021-87-11-11-18
- Grindlay G., Mora J., Gras L., de Loos-Vollebregt M.T. C. Atomic spectrometry methods for wine analysis: A critical evaluation and discussion of recent applications // Anal. Chim. Acta. 2011. V. 691. P. 18. https://doi.org/10.1016/j.aca.2011.02.050
- Hopfer H., Nelson J., Collins T.S., Heymann H., Ebeler S.E. The combined impact of vineyard origin and processing winery on the elemental profile of red wines // Food Chem. 2015. V. 172. P. 486. https://doi.org/10.1016/j.foodchem.2014.09.113
- Hill T., Lewicki P. Statistics Methods and Applications. Tulsa, OK USA: StatSoft, 2007. 719 p.
- Zinicovscaia I., Sturza R., Gurmeza I., Vergel K., Gundorina S., Duca G. Metal bioaccumulation in the soil–leaf–fruit system determined by neutron activation analysis // J. Food Meas. Charact. 2018. V. 13. P. 592. https://doi.org/10.1007/s11694-018-9972-4
- Amorós J.A., Pérez-de-los Reyes C., García Navarro F.J., Bravo S., Chacón J.L., Martínez J., Jiménez Ballesta R. Bioaccumulation of mineral elements in grapevine varieties cultivated in “La Mancha” // J. Soil Sci. Plant Nutr. 2013. V. 176. P. 843. https://doi.org/10.1002/jpln.201300015
- Nicolini G., Larcher R., Pangrazzi P., Bontempo L. Changes in the contents of micro- and trace-elements in wine due to winemaking treatments // Vitis – J. Grapevine Res. 2004. V. 43. P. 41. https://doi.org/10.5073/vitis.2004.43.41-45
- Da Silva J.M., da Silva G.H.T.G., Parente D.C., Leite F.C.B., Silva C.S., Valente P., et al. Biological diversity of carbon assimilation among isolates of the yeast Dekkera bruxellensis from wine and fuel-ethanol industrial processes // FEMS Yeast Res. 2019. V. 19. Artile foz022. https://doi.org/10.1093/femsyr/foz022
- Ren M., Liu S., Li R., You Y., Huang W., Zhan J. Clarifying effect of different fining agents on mulberry wine // Int. J. Food Sci. Technol. 2020. V. 55. P. 1578. https://doi.org/10.1111/ijfs.14433
- Geana E.I., Marinescu A., Iordache A.M., Sandru C., Ionete R.E., Bala C. Differentiation of Romanian wines on geographical origin and wine variety by elemental composition and phenolic components // Food Anal. Methods. 2014. V. 7. P. 2064. https://doi.org/10.1007/s12161-014-9846-2
- Temerdashev Z., Abakumov A., Bolshov M., Khalafyan A., Ageeva N., Vasilyev A. Data on the influence of clarification and stabilization with bentonite clays on the elemental composition of red wines determining their varietal affiliation // Data Brief. 2022. V. 42. Article 108163. https://doi.org/10.1016/j.dib.2022.108163
- Arozarena I., Casp A., Marin R., Navarro M. Differentiation of some Spanish wines according to variety and region based on their anthocyanin composition // Eur. Food Res. Technol. 2000. V. 212. P. 108. https://doi.org/10.1007/s002170000212
Дополнительные файлы
