电邮这篇文章 Magnetic anisotropy of single-ion magnet (PPh4)2[ReF6] · 2H2O
- 作者: Taran L.S1, Elfimova V.Y2, Streltsov S.V1,2
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隶属关系:
- M. N. Mikheev lnstitute of Metal Physics of Ural Branch of Russian Academy of Sciences
- Ural Federal University
- 期: 卷 117, 编号 7-8 (4) (2023)
- 页面: 612-613
- 栏目: Articles
- URL: https://vestnik.nvsu.ru/0370-274X/article/view/664140
- DOI: https://doi.org/10.31857/S1234567823080086
- EDN: https://elibrary.ru/WFEXQU
- ID: 664140
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详细
Studying of single-molecule magnets has sprung many surprises such as, e.g., quantum tunneling of the magnetization, which is strongly related to the presence of a magnetic anisotropy. Electron spin resonance and inelastic neutron scattering measurements of (PPh4)2[ReF6]⋅2H2O complex evidence an unprecedented large single-site magnetic anisotropy of D@35 K in this material. Using state-of-the-art ab initio calculations we found that the single-ion anisotropy is indeed very large (but does not exceed 12 K) and revealed the physical mechanism lying behind this phenomenon.
作者简介
L. Taran
M. N. Mikheev lnstitute of Metal Physics of Ural Branch of Russian Academy of Sciences
Email: letters@kapitza.ras.ru
V. Elfimova
Ural Federal University
Email: letters@kapitza.ras.ru
S. Streltsov
M. N. Mikheev lnstitute of Metal Physics of Ural Branch of Russian Academy of Sciences; Ural Federal University
编辑信件的主要联系方式.
Email: letters@kapitza.ras.ru
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