ENTALPY OF THE FORMATION OF DyTaO4 и HoTaO4 ORTHOTANTALATES

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Abstract

The enthalpies of dissolution of orthotantalates of dysprosium and holmium have been measured by the method of discharge calorimetry, on the basis of which the enthalpies of formation from oxides and from simple substances at a temperature of 298.15 K have been calculated. Based on the obtained values and literature values, the temperature dependences of the Gibbs energy of formation from oxides in the region of high temperatures were estimated.

About the authors

I. A. Bazhenova

Lomonosov Moscow State University

Email: i.risk.a91@mail.ru
Moscow, 119991, Russia

A. V. Guskov

N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: i.risk.a91@mail.ru
Moscow, Russia

P. G. Gagarin

N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: i.risk.a91@mail.ru
Moscow, Russia

V. N. Guskov

N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: i.risk.a91@mail.ru
Moscow, Russia

A. V. Khvan

Lomonosov Moscow State University

Email: i.risk.a91@mail.ru
Moscow, 119991, Russia

K. S. Gavrichev

N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Author for correspondence.
Email: i.risk.a91@mail.ru
Moscow, Russia

References

  1. Keller G. // Z. Anorg. Allg. Chem. 1962. V. 318. P. 89.
  2. Rooksby H.R., White E.A.D. // Acta Crystallogr. 1964. V. 16. P. 888. https://doi.org/10.1107/S0365110X63002395
  3. Арсеньев П.А., Глушкова В.Б., Евдокимов А.А. и др. Соединения редкоземельных элементов. Цирконаты, гафнаты, ниобаты, танталаты, антимонаты. М.: Наука, 1985. 261 с.
  4. Портной К.И., Тимофеева Н.И., Салибеков С.Е. // Изв. АНСССР. Неорган. материалы. 1970. Т. 6. С. 289.
  5. Osterloh F.E. // Chem. Mater. 2008. V. 20. № 1. P. 35. doi: 10.1021/cm7024203.
  6. Nyman M., Rodriguez M.A., Rohwer L.E. S., et al. // Chem. Mater.2009. V. 21. № 19. P. 4731. https://doi.org/10.1021/cm9020645.
  7. Brixner L.H., Chen H.// J. Electrochem. Soc. 1983. V. 130. № 12. P. 2435. https://doi.org/10.1149/1.2119609.
  8. Voloshyna O., Gerasimov J., Siletskiy O., et al. // Optical Mater. 2017. V.66. P. 332. doi: 10.1016/j.optmat.2017.02.037.
  9. Rozhdestvenskii F.A., Zuev M.G. // J. Lumin. 1983. V. 28. P. 465. https://doi.org/10.1016/0022-2313(83)90013-3
  10. Siqueira K.P.F., Carmo A.P., Bell M.J.V., Dias A. // J. Lumin. 2016. V. 179. P. 140. https://doi.org/10.1016/j.jlomin.2016.06.054
  11. Chen L., Hu M., Wu P., Feng J. // J. Am. Ceram. Soc. 2019. V. 102. P. 4809. doi: 10.1111/jace.16328
  12. Zhou Y., Gan G., Ge Z., Feng J. // Mater. Res. Express. 2020. V.7. P. 015204. doi: 10.1088/2053-1591/ab669f
  13. Chen L., Li B., Feng J.//Progress in Materials Science 2024. V. 144. P. 101265. https://doi.org/10.1016/j.pmatsci.2024.101265.
  14. Рождественский Ф.А., Зуев М.Г., Фатеев А.А. Танталаты трехвалентных металлов. М.: Наука, 1986. 168 с.
  15. Guskov A.V., Gavrichev K.S. // Rus. J. of Inorganic Chemistry. 2021. V. 66. № 13. P. 1947. doi: 10.1134/S0036023621130088
  16. Gagarin P.G., Guskov A.V., et al. // J. Am. Ceram. Soc. 2021.V.104. № 1. P. 472. doi: 10.1111/jace.17460.
  17. Gagarin P.G., Guskov A.V. et al. // Ceramics International 2021. V.47. P. 2892. https://doi.org/10.1016/j.ceramint.2020.09.072
  18. Yokogawa Y., Yoshimura M. // J. Am. Ceram. Soc. 1997. V.80. P. 1965. https://doi.org/10.1111/j.1151-2916.1997.tb03079.x.
  19. Panova T., Isupova E., Keler E.K. // Izv. Akad. Nauk SSSR, Neorg. Mater.(USSR). 1978. V.14.
  20. Teterin G., Menchuk E., Zinchenko V., Yeremina L. // Ukrainian Chem. J. 1996. V. 62. P. 9.
  21. Reznitskii L.A. // Inorganic Materials. 2001. V. 37. № 5. P. 491.
  22. Глушкова В.Б., Панова Т.И., Федоров Н.Ф., Келлер Э.К. // Неорган. материалы. 1976. Т. 12. № 7. С. 1258.
  23. Bajenova I.A., Guskov A.V., Gagarin P.G., et al. // J. Am. Ceram. Soc. 2023. V. 106. P. 3777.
  24. Uriano G. Standard Reference Material 720 Synthetic Sapphire (α-Al2O3). National Bureau of Standards Certificate.1982.
  25. Subramani T., Navrotsky A. // Inorg. Chem. 2019. V. 58. P. 16126. https://doi.org/10.1021/acs.inorgchem.9b02675.
  26. Yang S., Powell M., Kolis J.W., Navrotsky A. // J. of Solid State Chemistry. 2020. V. 287. P. 121344.
  27. Helean K., Navrotsky A. // J. of Thermal Analysis and Calorimetry. 2002. V. 69. P. 751.
  28. Ushakov S., Helean K., Navrotsky A., Boatner L. // J. of Materials Research. 2001. V. 16. P. 2623.
  29. Putnam R.L. Formation energetics of ceramic waste materials for the disposal of surplus weapons plutonium. Princeton University, 1999. 252 р.
  30. Robie R., Hemingway B., Fisher J. US Geol. Survey Bull. 1452, 1979.
  31. Qi J., Guo X., Mielewczyk-Gryn A., Navrotsky A. // J. of Solid State Chemistry. 2015. V. 227. P. 150.
  32. Mielewczyk-Gryn A., Navrotsky A. // American Mineralogist. 2015. V. 100. P. 1578.
  33. Hayun S., Lilova K., Salhov S., Navrotsky A. // Intermetallics. 2020. V. 125. P. 106897.
  34. Lepple M., Ushakov S.V., Lilova K. et al. // J. European Ceramic Society. 2021. V. 41. P. 1629. https://doi.org/10.1016/j.jeurceramsoc.2020.10.039.
  35. Zlotnik S., Sahu S.K., Navrotsky A., Vilarinho P.M. // Chemistry A European J. 2015. V. 21. P. 5231. https://doi.org/10.1002/chem.201405666.
  36. Forbes T.Z., Nyman M., Rodriguez M.A., Navrotsky A. // J. of Solid State Chemistry. 2010. V. 183. P. 2516. https://doi.org/10.1016/j.jssc.2010.08.024.
  37. McHale J.M., Navrotsky A., Kowach G.R. et al. // Chem. Mater. 1997. V. 9. P. 1538. https://doi.org/10.1021/cm970244r.
  38. Orr R.L.// J. Am. Chem. Soc. 1953. V. 75. P. 2808. https://doi.org/10.1021/ja01108a005.
  39. Shannon R.D. // Acta Crystallographica Section A: Crystal Physics, Diffraction, Theoretical and General Crystallography. 1976. V. 32. P. 751.
  40. Cordfunke E., Konings R. // Thermochimica Acta. 2001. V. 375. P. 65.
  41. Chase M.W. National Information Standards Organization (US), NIST-JANAF thermochemical tables, American Chemical Society Washington, DC, 1998.
  42. Konings R.J.M., Beneš O., Kovács A. et al. // J. Physical and Chemical Reference Data. 2014. V. 43. P. 013101–1–013101–95. https://doi.org/10.1063/1.4825256
  43. Jacob K.T., Chander Shekhar, Waseda Y. // J. Chem. Thermodynamics. 2009. V. 41. P. 748. doi: 10.1016/j.jct.2008.12.006
  44. Термические константы веществ./ Под ред. В.П. Глушко Справочник. Москва. 19651982. https://www.chem.msu.su/cgibin/tkv.pl?show=welcome.html&_ga
  45. Barin I. Thermochemical Data of Pure Substances. 3rd Edition. VCH – Weinheim, 1995, 2003 c.

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