Sorption capacity of polymer based on carboxymethylcellulose and glycidylacrylate towards metal ions

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Abstract

The sorption ability of the synthesized polymer based on carboxymethylcellulose and glycidylacrylate towards Cu2+, Ni2+, Fe2+, Mn2+ ions has been studied. It has been shown that the sorption of metal ions is reliably described by the Langmuir model, and the process itself has a physical character. By the method of thermogravimetric analysis it has been established that the process of thermodegradation of the polymer occurs in three steps, and of its complex with copper – ​in four steps. The activation energy of decomposition of the initial polymer for each step is in the range of 29–57 kJ/mol, and for its complex with copper – ​58–120 kJ/mol. The introduction of Cu(II) increases the thermostability of the obtained polymer based on carboxymethylcellulose.

About the authors

V. A. Lipin

Graduate School of Technology and Energy, St. Petersburg State University of Industrial Technologies and Design

St. Petersburg, Russia

A. N. Evdokimov

Graduate School of Technology and Energy, St. Petersburg State University of Industrial Technologies and Design

St. Petersburg, Russia

Ya. A. Petrova

Graduate School of Technology and Energy, St. Petersburg State University of Industrial Technologies and Design

Email: yulia.petrova1997@yandex.ru
St. Petersburg, Russia

D. D. Hernandez Garcia

Graduate School of Technology and Energy, St. Petersburg State University of Industrial Technologies and Design

St. Petersburg, Russia

I. V. Krasanov

St. Petersburg State Maritime Technical University

St. Petersburg, Russia

A. V. Dmitrieva

St. Petersburg State Maritime Technical University

St. Petersburg, Russia

V. E. Sitnikova

ITMO National Research University

St. Petersburg, Russia

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