Hydrothermal synthesis of bimetallic platinum-nickel powders and their structural characteristics

封面

如何引用文章

全文:

开放存取 开放存取
受限制的访问 ##reader.subscriptionAccessGranted##
受限制的访问 订阅存取

详细

The processes of combined reduction of platinum and nickel complex compounds from ammonia-alkaline aqueous solutions with hydrazine hydrate under hydrothermal autoclave conditions are studied. It was established that quantitative precipitation of nickel and platinum occurred within 1 hour at a temperature of 110°C. All phases formed during the reduction had the fcc lattices and exhibited ferromagnetic properties. X-ray phase analysis has proven the formation of solid platinum-nickel substitution solutions. The molar ratio of nickel to platinum was varied from 16/1 to 0.5/1, and in all cases the formation of two phases of the solid nickel-platinum substitution solution was found out: one of variable composition depending on the initial molar ratio of nickel and platinum, with a lattice parameter of 3.622–3.772 Å, which corresponds to 25–62 at. % of platinum; and the second one, enriched in platinum, of practically unchanged composition (90–95 at. %) with a parameter of 3.885–3.901 Å. At ratios from 16/1 to 1/1, in addition to two phases of the solid solution, a nickel phase with a crystal lattice parameter of 3.527 Å was clearly recorded. When the initial ratio of nickel to platinum was 0.5/1, an individual phase of metallic nickel was not detected. It was found that under hydrothermal conditions, nickel dissolved in a solution of 1 M hydrochloric acid, and solid solutions were chemically and structurally stable.

全文:

受限制的访问

作者简介

O. Belousov

Institute of Chemistry and Chemical Technology; Siberian Branch of the Russian Academy of Sciences, Siberian Federal University

Email: roma_boris@list.ru
俄罗斯联邦, Akademgorodok, 50/24, Krasnoyarsk, 660036; Svobodny Ave., 79, Krasnoyarsk, 660041

N. Belousova

Siberian Federal University

Email: roma_boris@list.ru
俄罗斯联邦, Svobodny Ave., 79, Krasnoyarsk, 660041

R. Borisov

Institute of Chemistry and Chemical Technology; Siberian Branch of the Russian Academy of Sciences, Siberian Federal University

编辑信件的主要联系方式.
Email: roma_boris@list.ru
俄罗斯联邦, Akademgorodok, 50/24, Krasnoyarsk, 660036; Svobodny Ave., 79, Krasnoyarsk, 660041

A. Zhizhaev

Institute of Chemistry and Chemical Technology, Siberian Branch of the Russian Academy of Sciences

Email: roma_boris@list.ru
俄罗斯联邦, Akademgorodok, 50/24, Krasnoyarsk, 660036

参考

  1. Behera A., Mittu B., Padhi S. et al. // Micro and Nano Technologies. 2020. P. 639. https://doi.org/10.1016/B978-0-12-821354-4.00025-X
  2. Zhou M., Li C., Fang J. // Chem. Rev. 2020. V. 121. № 2. P. 736. https://doi.org/10.1021/acs.chemrev.0c00436
  3. Ali S., Sharma A.S., Ahmad W. et al. // Crit. Rev. Anal. Chem. 2021. V. 51. № 5. P. 454. https://doi.org/10.1080/10408347.2020.1743964
  4. Ghosh Chaudhuri R., Paria S. // Chem. Rev. 2012. V. 112. № 4. P. 2373. https://doi.org/10.1021/cr100449n
  5. Mazhar T., Shrivastava V., Tomar R.S. // J. Pharm. Sci. Research. 2017. V. 9. № 2. P. 102.
  6. Wang C., Dragoe D., Colbeau-Justin C. et al. // ACS Appl. Mater. Interfасеs. 2023. V. 15. № 36. P. 42637. https://doi.org/10.1021/acsami.3c08842
  7. Соловьева А.Ю., Еременко Н.К., Образцова И.И. и др. // Журн. неорган. химии. 2018. Т. 63. № 4. С. 416. https://doi.org/10.7868/S0044457X18040049
  8. Schnedlitz M., Fernandez-Perea R., Knez D. et al. // J. Phys. Chem. C. 2019. V. 123. № 32. P. 20037. https://dx.doi.org/10.1021/acs.jpcc.9b05765
  9. Chen Y., Yang F., Dai Y. et al. // J. Phys. Chem. C. 2008. V. 112. № 5. P. 1645. https://doi.org/10.1021/jp709886y
  10. Chen Y., Liang Z., Yang F. et al. // J. Phys. Chem. C. 2011. V. 115. № 49. P. 24073. https://doi.org/10.1021/jp207828n
  11. Nadeem M., Yasin G., Bhatti M.H. et al. // J. Power Sources. 2018. V. 402. P. 34. https://doi.org/10.1016/j.jpowsour.2018.09.006
  12. Eiler K., Fornell J., Navarro-Senent C. et al. // Nanoscale. 2020. V. 12. № 14. P. 7749. https://doi.org/10.1039/C9NR10757F
  13. Nair K.G., Vishnuraj R., Pullithadathil B. // ACS Appl. Electron. Mater. 2021. V. 3. № 4. P. 1621. https://doi.org/10.1021/acsaelm.0c01103
  14. Li Y.J., Dong K., Ma X.K. et al. // Sep. Purif. Technol. 2023. V. 315. P. 123631. https://doi.org/10.1016/j.seppur.2023.123631
  15. Руднева Ю.В., Коренев С.В. // Журн. неорган. химии. 2024. Т. 69. № 8. С. 1181. https://doi.org/10.31857/S0044457X24080112
  16. Бумагин Н.А. // Журн. общей химии. 2023. Т. 93. № 2. С. 332. https://doi.org/10.1134/S1070363223020147
  17. Shamsabadi A., Haghighi T., Carvalho S. et al. // Adv. Mater. 2023. V. 36. № 10. P. 2300184. https://doi.org/10.1002/adma.202300184
  18. Da Silva C.M., Amara H., Fossard F. et al. // Nanoscale. 2022. V. 14. № 27. P. 9832. https://doi.org/10.1039/D2NR02478K
  19. Peng C., Pang R., Li J. et al. // Adv. Mater. 2023. V. 36. № 10. P. 2211724. https://doi.org/10.1002/adma.202211724
  20. Рашидова С.Ш., Вохидова Н.Р., Алексеева О.В. // Журн. неорган. химии. 2012. Т. 67. № 12. С. 1851. https://doi.org/10.31857/S0044457X22601146
  21. Godínez-Salomón F., Hallen-López M., Solorza-Feria O. // Int. J. Hydrogеn Energy. 2012. V. 37. № 19. P. 14902. https://doi.org/10.1016/j.ijhydene.2012.01.157
  22. Zhao Y., Yang X., Tian J. et al. // Int. J. Hydrogеn Energy. 2010. V. 35. № 8. P. 3249. https://doi.org/10.1016/j.ijhydene.2010.01.112
  23. Wang R., Wang H., Luo F. et al. // Electrochem. Energy Rev. 2018. V. 1. P. 324. https://doi.org/10.1007/s41918-018-0013-0
  24. Dahmani C.E., Cadeville M.C., Sanchez J.M. et al. // Phys. Rev. Lett. 1985. V. 55. № 11. P. 1208. https://doi.org/10.1103/PhysRevLett.55.1208
  25. Федоров П.П., Попов А.А., Шубин Ю.В. и др. // Журн. неорган. химии. 2022. Т. 67. № 12. С. 1805. https://doi.org/10.31857/S0044457X22600748
  26. Логутенко О.А., Титков А.И., Воробьев А.М. и др. // Журн. общей химии. 2018. Т. 88. № 2. С. 311.
  27. Борисов Р.В., Белоусов О.В., Лихацкий М.Н. и др. // Журн. неорган. химии. 2023. Т. 68. № 11. С. 1537. https://doi.org/10.31857/S0044457X23600573
  28. Zakharov Y.A., Pugachev V.M., Bogomyakov A.S. et al. // J. Phys. Chem. C. 2019. V. 124. № 1. P. 1008. https://doi.org/10.1021/acs.jpcc.9b07897
  29. Белоусов О.В., Борисов Р.В., Белоусова Н.В. и др. // Журн. неорган. химии. 2021. Т. 66. № 10. С. 1380. https://doi.org/10.31857/S0044457X21100032
  30. Фесик Е.В., Буслаева Т.М., Мельникова Т.И. др. // Неорган. материалы. 2018. Т. 54. № 12. С. 1363. https://doi.org/10.1134/S0002337X18120035
  31. Pinchujit S., Phuruangrat A., Wannapop S. et al. // Russ. J. Inorg. Chem. 2022. V. 67 (Suppl. 2). Р. S199. https://doi.org/10.1134/S0036023622602148
  32. Симоненко Т.Л., Дудорова Д.А., Симоненко Н.П. и др. // Журн. неорган. химии. 2023. Т. 68. № 12. С. 1849. https://doi.org/10.31857/S0044457X23601591
  33. Поляков Е.В., Цуканов Р.Р., Булдакова Л.Ю. и др. // Журн. неорган. химии. 2022. Т. 67. № 6. С. 852. https://doi.org/10.31857/S0044457X22060204
  34. Васильченко Д.Б., Комаров В.Ю., Ткачев С.В. и др. // Журн. неорган. химии. 2022. Т. 67. № 12. С. 1707. https://doi.org/10.31857/S0044457X22601018
  35. Воробьев А.М., Титков А.И., Логутенко О.А. // Журн. общей химии. 2022. Т. 92. № 3. С. 484. https://doi.org/10.31857/S0044460X22030106
  36. Тупикова Е.Н., Платонов И.А., Бондарева О.С. и др. // Кинетика и катализ. 2021. Т. 62. № 6. С. 803. https://doi.org/10.31857/S0453881121060186
  37. Wang Y., Yan R., Xiang Q. et al. // Chem. Select. 2023. V. 8. № 41. P. e202303718. https://doi.org/10.1002/slct.202303718
  38. Wang K., Wang Y., Geng S. et al. // Adv. Funct. Mater. 2022. V. 32. № 22. P. 2113399. https://doi.org/10.1002/adfm.202113399
  39. Leteba G.M., Mitchell D.R., Levecque P.B. et al. // ACS Appl. Nano Mater. 2020. V. 3. № 6. P. 5718. https://doi.org/10.1021/acsanm.0c00915
  40. Liu X., Xu G., Chen Y. et al. // Sci. Rep. 2015. V. 5. № 1. P. 7619. https://doi.org/10.1038/srep07619
  41. Li Y.J., Dong K., Ma X.K. et al. // Sep. Purif. Technol. 2023. V. 315. P. 123631. https://doi.org/10.1016/j.seppur.2023.123631
  42. Белоусова Н.В., Белоусов О.В., Борисов Р.В. и др. // Изв. вузов. Цветная металлургия. 2023. Т. 29. № 5. С. 15. https://doi.org/10.17073/0021-3438-2023-5-15-24
  43. Belousov O.V., Belousova N.V., Sirotina A.V. et al. // Langmuir. 2011. V. 27. № 18. P. 11697. https://doi.org/10.1021/la202686x
  44. Конин Г.А., Большаков А.М., Хмелевская Л.В. // Коорд. химия. 1996. Т. 22. № 12. C. 928.

补充文件

附件文件
动作
1. JATS XML
下载
2. Fig. 1. Fragments of X-ray diffraction patterns of sample 4: 1 – synthesized for 1 hour at a temperature of 110°C, molar ratio nNi : nPt = 4 : 1; 2 – material after treatment of the solid phase with 1 M hydrochloric acid.

下载 (196KB)
索引源数据
3. Fig. 2. Dependence of the crystal lattice parameter of the β-phase on the logarithm of the molar ratio Ni: Pt.

下载 (43KB)
索引源数据
4. Рис. 3. Зависимость количества фазы Ni(0) в твердой фазе от логарифма мольного соотношения Ni : Pt.

下载 (43KB)
索引源数据
5. Fig. 4. SEM image, element distribution maps and Ni:Pt atomic ratio at different points: a – sample 4; b – sample 7.

下载 (655KB)
索引源数据
6. Fig. 5. SEM image of Ni, Pt material, sample 4 after treatment in 1 M HCl.

下载 (313KB)
索引源数据

版权所有 © Russian Academy of Sciences, 2025