Spin States of Cobalt Ions in the Bulk and on the Surface of LaCoO3 Probed by X-ray Absorption, Emission, and Photoelectron Spectra

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

We present X-ray photoelectron, Co L2,3">L2,3 and O K X-ray absorption, as well as Co Kβ1,3">Kβ1,3 X-ray emission spectroscopy results of studies of the spin states of trivalent cobalt ions in single-crystal cobaltite LaCoO3. We show that at room temperature, in the bulk of a LaCoO3 single crystal, Co3+ ions are in the low-spin state, while high-spin Co2+, high-spin Co3+, low-spin Co3+, and probably also intermediate-spin Co3+ ions are located on the surface.

Авторлар туралы

V. Galakhov

Mikheev Institute of Metal Physics, Ural Branch, Russian Academy of Sciences

Email: solin@imp.uran.ru
620108, Yekaterinburg, Russia

M. Udintseva

Mikheev Institute of Metal Physics, Ural Branch, Russian Academy of Sciences

Email: galakhov@gmail.com
Yekaterinburg, 620108 Russia

D. Smirnov

Dresden University of Technology

Email: galakhov@gmail.com
Dresden, 01062 Germany

A. Makarova

Physikalische Chemie Institut f¨ur Chemie und Biochemie Freie Universita¨at Berlin

Email: galakhov@gmail.com
Berlin, 14195 Germany

K. Kyupper

University of Osnabru¨uck

Хат алмасуға жауапты Автор.
Email: galakhov@gmail.com
Osnabrück, 49076 Germany

Әдебиет тізімі

  1. G. Jonker and J.V. Santen, Physica 19, 120 (1953).
  2. P.M. Raccah and J. B. Goodenough, Phys. Rev. 155, 932 (1967).
  3. G. Thornton, B. Tofield, and D. Williams, Solid State Commun. 44, 1213 (1982).
  4. S.R. English, J. Wu, and C. Leighton, Phys. Rev. B 65, 220407 (2002).
  5. M.A. Korotin, S.Y. Ezhov, I.V. Solovyev, V. I. Anisimov, D. I. Khomskii, and G.A. Sawatzky, Phys. Rev. B 54, 5309 (1996).
  6. S. Yamaguchi, Y. Okimoto, and Y. Tokura, Phys. Rev. B 55, R8666 (1997).
  7. P.G. Radaelli and S.-W. Cheong, Phys. Rev. B 66, 094408 (2002).
  8. I.A. Nekrasov, S.V. Streltsov, M.A. Korotin, and V. I. Anisimov, Phys. Rev. B 63, 235113 (2003).
  9. G. Maris, Y. Ren, V. Volotchaev, C. Zobel, T. Lorenz, and T.T.M. Palstra, Phys. Rev. B 67, 224423 (2003).
  10. M. Magnuson, S. M. Butorin, C. S˚athe, J. Nordgren, and P. Ravindran, Europhys. Lett. 68, 289 (2004).
  11. D. Phelan, D. Louca, S. Rosenkranz, S.-H. Lee, Y. Qiu, P. J. Chupas, R. Osborn, H. Zheng, J. F. Mitchell, J.R.D. Copley, J. L. Sarrao, and Y. Moritomo, Phys. Rev. Lett. 96, 027201 (2006).
  12. G. Vank'o, J.-P. Rueff, A. Mattila, Z. N'emeth, and A. Shukla, Phys. Rev. B 73, 024424 (2006).
  13. R. F. Klie, J.C. Zheng, Y. Zhu, M. Varela, J. Wu, and C. Leighton, Phys. Rev. Lett. 99, 047203 (2007).
  14. V.V. Sikolenko, S. L. Molodtsov, M. Izquierdo, I.O. Troyanchuk, D. Karpinsky, S. I. Tiutiunnikov, E. Efimova, D. Prabhakaran, D. Novoselov, and V. Efimov, Physica B: Condens. Matter. 536, 597 (2018).
  15. В. В. Сиколенко, И.О. Троянчук, Д.В. Карпинский, A. Rogalev, F.Wilhelm, R. Rosenberg, D. Prabhakaran, E.А. Ефимова, В.В. Ефимов, С.И. Тютюнников, И.А. Бобриков, Физика твердого тела 60, 283 (2018)
  16. V.V. Sikolenko, I.O. Troyanchuk, D.V. Karpinsky, A. Rogalev, F.Wilhelm, R. Rosenberg, D. Prabhakaran, E.A. Efimova, V.V. Efimov, S. I. Tiutiunnikov, and I.A. Bobrikov, Phys. Solid State 60, 288 (2018).
  17. M. Feygenson, D. Novoselov, S. Pascarelli, R. Chernikov, O. Zaharko, F. Porcher, D. Karpinsky, A. Nikitin, D. Prabhakaran, A. Sazonov, and V. Sikolenko, Phys. Rev. B 100, 054306 (2019).
  18. M. Zhuang, W. Zhang, and N. Ming, Phys. Rev. B 57, 10705 (1998).
  19. S. Noguchi, S. Kawamata, K. Okuda, H. Nojiri, and M. Motokawa, Phys. Rev. B 66, 094404 (2002).
  20. K. Kn'ıˇzek, J. Hejtm'anek, and P. Nov'ak, J. Phys. Condens. Matter 18, 3285 (2006).
  21. A. Podlesnyak, S. Streule, J. Mesot, M. Medarde, E. Pomjakushina, K. Conder, A. Tanaka, M.W. Haverkort, and D. I. Khomskii, Phys. Rev. Lett. 97, 247208 (2006).
  22. M.W. Haverkort, Z. Hu, J.C. Cezar, T. Burnus, H. Hartmann, M. Reuther, C. Zobel, T. Lorenz, A. Tanaka, N.B. Brookes, H.H. Hsieh, H.-J. Lin, C.T. Chen, and L.H. Tjeng, Phys. Rev. Lett. 97, 176405 (2006).
  23. M. Medarde, C. Dallera, M. Grioni, J. Voigt, A. Podlesnyak, E. Pomjakushina, K. Conder, T. Neisius, O. Tjernberg, and S.N. Barilo, Phys. Rev. B 73, 054424 (2006).
  24. N. Sundaram, Y. Jiang, I.E. Anderson, D.P. Belanger, C.H. Booth, F. Bridges, J. F. Mitchell, T. Proffen, and H. Zheng, Phys. Rev. Lett. 102, 026401 (2009).
  25. K. Kn'ıˇzek, J. Hejtm'anek, Z. Jir'ak, P. Tomeˇs, P. Henry, and A. Andr'e, Phys. Rev. B 79, 134103 (2009).
  26. V. Kˇr'apek, P. Nov'ak, J. Kuneˇs, D. Novoselov, D.M. Korotin, and V. I. Anisimov, Phys. Rev. B 86, 195104 (2012).
  27. Р.Ю. Бабкин, К.В. Ламонова, С.М. Орел, С. Г. Овчинников, Ю. Г. Пашкевич, Письма в ЖЭТФ 99, 547 (2014)
  28. R.Yu. Babkin, K.V. Lamonova, S.M. Orel, S.G. Ovchinnikov, and Yu.G. Pashkevich, JETP Lett. 99, 476 (2014).
  29. S.R. Barman and D.D. Sarma, Phys. Rev. B 49, 13979 (1994).
  30. S.K. Pandey, A. Kumar, S. Patil, V.R.R. Medicherla, R. S. Singh, K. Maiti, D. Prabhakaran, A.T. Boothroyd, and A.V. Pimpale, Phys. Rev. B 77, 045123 (2008).
  31. Z. Shen, M. Qu, J. Shi, F. E. Oropeza, V.A. de la Pena O'Shea, G. Gorni, C. Tian, J. P. Hofmann, J. Cheng, J. Li, and K.H. Zhang, J. Energy Chem. 65, 637 (2022).
  32. J. Suntivich, W.T. Hong, Y.-L. Lee, J.M. Rondinelli, W. Yang, J. B. Goodenough, B. Dabrowski, J.W. Freeland, and Y. Shao-Horn, J. Phys. Chem. C 118, 1856 (2014).
  33. E. Stavitski and F.M. F. de Groot, Micron 41, 687 (2010).
  34. R.P. Vasquez, Phys. Rev. B 54, 14938 (1996).
  35. T. Saitoh, T. Mizokawa, A. Fujimori, M. Abbate, Y. Takeda, and M. Takano, Phys. Rev. B 55, 4257 (1997).
  36. K.A. Stoerzinger,W.T. Hong, E. J. Crumlin, H. Bluhm, M.D. Biegalski, and Y. Shao-Horn, J. Phys. Chem. C 118, 19733 (2014).
  37. B.W. Veal and D. J. Lam, J. Appl. Phys. 49, 1461 (1978).
  38. L. Richter, S.D. Bader, and M. B. Brodsky, Phys. Rev. B 22, 3059 (1980).
  39. J. Kemp, D. Beal, and P. Cox, J. Solid State Chem. 86, 50 (1990).
  40. M. Abbate, J.C. Fuggle, A. Fujimori, L.H. Tjeng, R.P.C.T. Chen, G.A. Sawatzky, H. Eisaki, and S. Uchida, Phys. Rev. B 47, 16124 (1993).
  41. L. Heymann, M. L. Weber, M. Wohlgemuth, M. Risch, R. Dittmann, C. Baeumer, and F. Gunkel, ACS Appl. Mater. Interfaces 14, 14129 (2022).
  42. D. Takegami, L. Nicola¨ı, T.C. Koethe, D. Kasinathan, C.Y. Kuo, Y.F. Liao, K.D. Tsuei, G. Panaccione, F. Offi, G. Monaco, N.B. Brookes, J. Min'ar, and L.H. Tjeng, Phys. Rev. B 99, 165101 (2019).
  43. T.Y. Ma, S. Dai, M. Jaroniec, and S. Z. Qiao, J. Amer. Chem. Soc. 136, 13925 (2014).
  44. L. Xu, Q. Jiang, Z. Xiao, X. Li, J. Huo, S. Wang, and L. Dai, Angew. Chem. Int. Ed. Engl. 55, 5277 (2016).
  45. Y. Liu, X. Kong, X. Guo, Q. Li, J. Ke, R. Wang, Q. Li, Z. Geng, and J. Zeng, ACS Catal. 10, 1077 (2020).
  46. A. Hariki, A. Yamanaka, and T. Uozumi, J. Phys. Soc. Jpn. 84, 073706 (2015).
  47. S. L. Wachowski, I. Szpunar, M.H. Sørby, A. Mielewczyk-Gry'n, M. Balaguer, C. Ghica, M.C. Istrate, M. Gazda, A.E. Gunnæs, J.M. Serra, T. Norby, and R. Strandbakke, Acta Mater. 199, 297 (2020).
  48. I. Szpunar, R. Strandbakke, M.H. Sørby, S. L. Wachowski, M. Balaguer, M. Tarach, J. Serra, A. Witkowska, E. Dzik, T. Norby, M. Gazda, and A. Mielewczyk-Gry'n, Materials 13, 4044 (2020).
  49. В. Р. Галахов, М.С. Удинцева, С. В. Наумов, С.Н. Шамин, Б.А. Гижевский, Письма в ЖЭТФ 116, 358 (2022)
  50. V.R. Galakhov, M. S. Udintseva, S.V. Naumov, S.N. Shamin, and B.A. Gizhevskii, JETP Lett. 116, 367 (2022).
  51. M. Garc'ıa-Fern'andez, V. Scagnoli, U. Staub, A.M. Mulders, M. Janousch, Y. Bodenthin, D. Meister, B.D. Patterson, A. Mirone, Y. Tanaka, T. Nakamura, S. Grenier, Y. Huang, and K. Conder, Phys. Rev. B 78, 054424 (2008).
  52. Z. Hu, H. Wu, M.W. Haverkort, H.H. Hsieh, H. J. Lin, T. Lorenz, J. Baier, A. Reichl, I. Bonn, C. Felser, A. Tanaka, C.T. Chen, and L.H. Tjeng, Phys. Rev. Lett. 92, 207402 (2004).
  53. C. S. Knee, D. J. Price, M.R. Lees, and M.T. Weller, Phys. Rev. B 68, 174407 (2003).
  54. J.-P. Rueff, C.-C. Kao, V.V. Struzhkin, J. Badro, J. Shu, R. J. Hemley, and H.K. Mao, Phys. Rev. Lett. 82, 3284 (1999).
  55. G. Vank'o, T. Neisius, G. Moln'ar, F. Renz, S. K'arp'ati, A. Shukla, and F.M. F. de Groot, J. Phys. Chem. B 110, 11647 (2006).
  56. J. Herrero-Mart'ın, J. L. Garc'ıa-Munoz, K. Kvashnina, E. Gallo, G. Sub'ıas, J.A. Alonso, and A. J. Bar'on- Gonz'alez, Phys. Rev. B 86, 125106 (2012).
  57. J.-M. Chen, Y.-Y. Chin, M. Valldor, Z. Hu, J.-M. Lee, S.-C. Haw, N. Hiraoka, H. Ishii, C.-W. Pao, K.-D. Tsuei, J.-F. Lee, H.-J. Lin, L.-Y. Jang, A. Tanaka, C.-T. Chen, and L.H. Tjeng, J. Am. Chem. Soc. 136, 1514 (2014).

Қосымша файлдар

Қосымша файлдар
Әрекет
1. JATS XML
Жүктеу

© Российская академия наук, 2023